Preheat your oven to 350°F and position the rack in the lower third—this matters because heat rises, and you want bottom caramelization before the top sets. Place a 9-inch cast iron skillet on the stovetop over medium heat for one full minute before adding butter.
Once the cast iron is warm, add the 1 tablespoon melted butter, then scatter the brown sugar and drizzle the honey directly over it. Stir constantly for two minutes—this is your foundation, and I always confess I used to rush here and ended up with gritty texture instead of glossy amber.
Arrange your peach slices in a circular pattern, overlapping slightly, pressing gently into the caramel base. The pressure matters because fruit settling releases juices that marry with sugar, creating that stunning seasonal summer color you're after. Remove from heat immediately.
In a separate bowl, whisk together flour, baking powder, and salt—this step aerates your dry mixture, which is why sifting feels fussy but actually prevents dense pockets. Set aside.
Cream the 1/2 cup butter and granulated sugar together for exactly three minutes using a hand mixer—I time this because undermixing leaves a grainy crumb structure. The mixture should look pale and noticeably fluffy. This is where air incorporation happens.
Beat in eggs one at a time, then add vanilla bean seeds and mix for thirty seconds after each addition. Those vanilla seeds look decorative, but they're delivering real vanilla compounds that extract can't match. Alternate adding your dry mixture and milk in three additions, starting and ending with dry ingredients—this technique prevents overmixing, which toughens cake.
Pour batter gently over the peaches, smoothing the top with a spatula without pressing down into the fruit layer. Transfer the skillet to the 350°F oven and bake for exactly 40 minutes, until a toothpick inserted into cake (not fruit) comes out with just a few moist crumbs clinging to it.
Cool in the skillet for ten minutes—this waiting period lets the caramel set enough to hold together during flipping. Run a thin knife around the edges to loosen any stuck spots, then place your serving platter over the skillet and flip decisively in one smooth motion. Leave the skillet on top for one minute, then lift away slowly.